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The amidine complexes cis-[L2PtNH[double bond, length as m-dash]C(R){1-MeCy(-2H)}]NO3 (R = Me, 1a; Ph, 1b, Me3C, 1c; Ph2(H)C, 1d) and cis-[L2PtNH[double bond, length as m-dash]C(R){9-MeAd(-2H)}]NO3 (R = Me, 2a; Ph, 2b; Me3C, 2c; Ph2(H)C, 2d), are formed when cis-[L2Pt(μ-OH)]2(NO3)2 (L = PPh3) reacts with 1-methylcytosine (1-MeCy) and 9-methyladenine (9-MeAd) in solution of MeCN, PhCN, Me3CCN and Ph2(H)CCN. Reaction of 1a,b and 2a,b with HCl affords the protonated amidines [NH2[double bond, length as m-dash]C(R){1-MeCy(-H)}]NO3 (R = Me, 3a; Ph, 3b) and [NH2[double bond, length as m-dash]C(R){9-MeAd(-H)}]NO3 (R = Me, 4a; Ph, 4b) and cis-(PPh3)2PtCl2 in quantitative yield. Treatment of 3b and 4b with NaOH allows the isolation of the neutral benzimidamides NH2-C(Ph){1-MeCy(-2H)} (5b) and NH2-C(Ph){9-MeAd(-2H)} (6b). In the solid state 3b shows a planar structure with the hydrogen atom on N(4) cytosine position involved in a strong H-bond with the NO3− ion. Intermolecular H-bonds between...
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