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Displaying Results 76 - 100 of 6866 on page 4 of 275
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2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide
(2009)
Gallagher, John F.; Alley, Steven; Lough, Alan J.
2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide
(2009)
Gallagher, John F.; Alley, Steven; Lough, Alan J.
Abstract:
The title compound, [Fe2(C5H5)2(C30H22N2O2)], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methylpyridine, forms a twisted molecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intramolecular C-H...[pi] interaction is observed involving a substituted [eta]5-C5H4 ring and an ortho H atom of the benzene ring on the opposite side of the molecule. In the crystal structure, there are no classical hydrogen bonds: interactions comprise a short C6-H...[pi](C6) interaction involving substituted benzene rings and two C-H...O=C interactions per molecule.
http://doras.dcu.ie/2442/
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2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide
(2010)
Gallagher, John F.; Alley, Steven; Lough, Alan J.
2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide
(2010)
Gallagher, John F.; Alley, Steven; Lough, Alan J.
Abstract:
The title compound, [Fe(C5H5)(C18H15N2O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N-H...N interactions with graph set R22(8), and are further augmented via intramolecular C-H...O=C and interdimer C-H...[pi](arene) interactions. Dimers are linked into chains along the [102] direction via weak C-H...O hydrogen bonds.
http://doras.dcu.ie/15329/
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2-Fluoro-N-(2-fluorobenzoyl)-N-(2-pyridyl)benzamide
(2009)
Gallagher, John F.; Donnelly, Katie; Lough, Alan J.
2-Fluoro-N-(2-fluorobenzoyl)-N-(2-pyridyl)benzamide
(2009)
Gallagher, John F.; Donnelly, Katie; Lough, Alan J.
Abstract:
The title compound, C19H12F2N2O2, a 2:1 product of the reaction of 2-fluorobenzoyl chloride and 2-aminopyridine, crystallizes with a disordered 2-fluorobenzene ring adopting two conformations [ratio of occupancies = 0.930 (4):0.070 (4)] in one of the two independent molecules (differing slightly in conformation) comprising the asymmetric unit. In the crystal structure, C-H...O and C-H...[pi](arene) interactions are present.
http://doras.dcu.ie/2397/
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2,2'-[2,3-Dihydro-2-(prop-2-enyl)-1H-isoindole-1,3-diylidene]bis(propanedinitrile)-tetrathiafulvalene (1/1), TCPI-TTF
(2002)
Crean, Colm; Gallagher, John F.; Pratt, Albert C.
2,2'-[2,3-Dihydro-2-(prop-2-enyl)-1H-isoindole-1,3-diylidene]bis(propanedinitrile)-tetrathiafulvalene (1/1), TCPI-TTF
(2002)
Crean, Colm; Gallagher, John F.; Pratt, Albert C.
Abstract:
The title complex, C17H9N5•C6H4S4, contains -deficient bis(dinitrile) and TTF molecules stacked alternately in columns along the a-axis direction; the interplanar angle between the TTF molecule and the isoindolinyl C4N[C(CN)2]2 moiety is 1.21 (4)°. The N-allyl moiety in the TCPI molecule is oriented at an angle of 87.10 (10)° with respect to the five-membered C4N ring, and the four C N bond lengths range from 1.134 (3) to 1.142 (3) Å, with C-C N angles in the range 174.3 (3)-176.9 (2)°. In the TTF system, the S-C bond lengths are 1.726 (3)-1.740 (3) and 1.751 (2)-1.763 (2) Å for the external S-C(H) and internal S-C(S) bonds, respectively.
http://doras.dcu.ie/22/
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2,2'-{2-[(E)-3-Phenylprop-2-enyl]-2,3-dihydro-1H-isoindol-1,3-diylidene}dimalononitrile, a π-deficient system for π...π (1:1) stacking investigations
(2001)
Crean, Colm; Gallagher, John F.; Pratt, Albert C.
2,2'-{2-[(E)-3-Phenylprop-2-enyl]-2,3-dihydro-1H-isoindol-1,3-diylidene}dimalononitrile, a π-deficient system for π...π (1:1) stacking investigations
(2001)
Crean, Colm; Gallagher, John F.; Pratt, Albert C.
Abstract:
The title compound, C₂₃H₁₃N₅, derived from cinnamyl alcohol and 2,2'-(isoindolin-1,3-diylidene)bispropanedinitrile, is a heterocyclic TCNQ analogue of interest as an electron-deficient component in charge-transfer complexes. A small perturbation of the four C-C≡N angles from linearity is observed, which are in the range 173.41 (18)-176.3 (2)°; the C≡N bond lengths are in the range 1.144 (2)-1.146 (2) Å. The terminal phenyl group is oriented at an angle of 77.17 (6)° to the C₄N ring and the C=C bond is short, 1.319 (2) Å. There are no classical hydrogen bonds, although intramolecular C-H...N and intermolecular C-H...π(arene) interactions influence the crystal-structure packing.
http://doras.dcu.ie/154/
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2,3-Difluoro-N-(2-pyridyl)benzamide
(2008)
Gallagher, John F.; McMahon, Joyce; Anderson, Frankie P.; Lough, Alan J.
2,3-Difluoro-N-(2-pyridyl)benzamide
(2008)
Gallagher, John F.; McMahon, Joyce; Anderson, Frankie P.; Lough, Alan J.
Abstract:
The title compound, C12H8F2N2O, crystallizes with two independent molecules in the asymmetric unit. The independent molecules differ slightly in conformation; the dihedral angles between the benzene and pyridine rings are 51.58 (5) and 49.97 (4)°. In the crystal structure, molecules aggregate via N-H...Npyridine interactions as hydrogen-bonded dimers with the structural motif R22(8), and these dimers are linked via C-H...O interactions to form a supramolecular chain.
http://doras.dcu.ie/2169/
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3 PLY: exploring the limits and possibilities for transformative workplace learning in Irish schools
(2014)
Kamp, Annelies; Black, Dorothy
3 PLY: exploring the limits and possibilities for transformative workplace learning in Irish schools
(2014)
Kamp, Annelies; Black, Dorothy
Abstract:
In this paper we report on preliminary research conducted in the Republic of Ireland and Northern Ireland by researchers at Dublin City University and the University of Ulster. The research considered the limits and possibilities for meaningful workplace learning for young people to support their transition to sustainable employment in the post-Global Financial Crisis context. In the research, we adopted the term ‘workplace learning’ as opposed to the term ‘workbased learning’ as it underscores our interest in learning that happens in a real workplace rather than learning that might happen in schools while targeted at future work endeavours. Our specific focus was on the forms of workplace learning that are organized within the context of the senior school curriculum and their role in enhancing youth transition and a consideration of what concepts from Actor Network Theory (Latour 2007) might offer in analysing the data. Funded by the Irish Standing Conference on Teacher Education...
http://doras.dcu.ie/20270/
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3-(Benzo[b]thien-2-yl)-5,6-dihydro-1,4,2-oxathiazine 4-Oxide
(1997)
Gallagher, John F.; Ferguson, George; Brouwer, Walter G.
3-(Benzo[b]thien-2-yl)-5,6-dihydro-1,4,2-oxathiazine 4-Oxide
(1997)
Gallagher, John F.; Ferguson, George; Brouwer, Walter G.
Abstract:
The title compound, C₁₁H₉NO₂S₂, is a potent material preservative and contains the 1,4,2-oxathiazine ring system in a half-chair conformation with the methylene C atoms 0.510 (3) and -0.367 (3) Å from the plane of the other four oxathiazine ring atoms.
http://doras.dcu.ie/565/
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3-D animation and morphing using RenderMan
(1996)
Foley, Somhairle
3-D animation and morphing using RenderMan
(1996)
Foley, Somhairle
Abstract:
A Websters dictionary definition of the word ‘animate’ strikes to the heart of what animation is about - the illusion of life Giving life to a sequence of pictures is the purpose of animation. This has been practised for over a century and nowadays computers are being used to create animations faster and more accurately than ever before Animations are no longer restricted to 'funnies', but can also be models of real-life situations. These are based on data not images, and the final images are generated after the data has been processed for unambiguous visualization. By representing the data in three dimensions it can be viewed in any number of ways according to the wishes of the 'end' user. RenderMan allows a scene to be viewed when defined m three dimensions. This can then be viewed as an animated sequence where special effects - such as the metamorphosis of objects (morphing) - may take place to provide a photorealistic animation. This thesis will examine how ...
http://doras.dcu.ie/18736/
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3-Fluoro-N-(3-fluorobenzoyl)-N-(2-pyridyl)benzamide
(2009)
Gallagher, John F.; Donnelly, Katie
3-Fluoro-N-(3-fluorobenzoyl)-N-(2-pyridyl)benzamide
(2009)
Gallagher, John F.; Donnelly, Katie
Abstract:
The title compound, C19H12F2N2O2, a 2:1 product of the reaction of 3-fluorobenzoylchloride and 2-aminopyridine crystallizes with a disordered 3-fluorobenzene ring adopting two conformations [ratio of occupancies 0.959 (4):0.041 (4)]. In the crystal structure, there are no classical hydrogen bonds and interactions comprise C-H...O in the form 2(C-H)...O=C [with motif R21(5)]; C-H...[pi](arene) interactions are also present.
http://doras.dcu.ie/2254/
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3D estimation and visualization of motion in a multicamera network for sports
(2011)
Kelly, Philip; O'Connor, Noel E.
3D estimation and visualization of motion in a multicamera network for sports
(2011)
Kelly, Philip; O'Connor, Noel E.
Abstract:
In this work, we develop image processing and computer vision techniques for visually tracking a tennis ball, in 3D, on a court instrumented with multiple low cost IP cameras. The technique first extracts 2D ball track data from each camera view, using object tracking methods. Next, an automatic feature- based video synchronization method is applied. This technique uses both the extracted 2D ball information from two or more camera views, plus camera calibration information. Then, in order to find 3D trajectory, the temporal 3D locations of the ball is estimated using triangulation of correspondent 2D locations obtained from automatically synchronized videos. Furthermore, we also incorporate a physics-based trajectory model into the system to improve the continuity of the tracked 3D ball during times when no two cameras have overlapping views of the ball location. The resultant 3D ball tracks are then visualized in a virtual 3D graphical environment. Finally, we quantify the accurac...
http://doras.dcu.ie/16575/
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3D facial landmark localization using combinatorial search and shape regression
(2012)
Sukno, Federico M.; Waddington, John L.; Whelan, Paul F.
3D facial landmark localization using combinatorial search and shape regression
(2012)
Sukno, Federico M.; Waddington, John L.; Whelan, Paul F.
Abstract:
This paper presents a method for the automatic detection of facial landmarks. The algorithm receives a set of 3D candidate points for each landmark (e.g. from a feature detector) and performs combinatorial search constrained by a deformable shape model. A key assumption of our approach is that for some landmarks there might not be an accurate candidate in the input set. This is tackled by detecting partial subsets of landmarks and inferring those that are missing so that the probability of the deformable model is maximized. The ability of the model to work with incomplete information makes it possible to limit the number of candidates that need to be retained, substantially reducing the number of possible combinations to be tested with respect to the alternative of trying to always detect the complete set of landmarks. We demonstrate the accuracy of the proposed method in a set of 144 facial scans acquired by means of a hand-held laser scanner in the context of clinical craniofacial...
http://doras.dcu.ie/18572/
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3D image analysis for pedestrian detection
(2006)
Kelly, Philip; Cooke, Eddie; O'Connor, Noel E.; Smeaton, Alan F.
3D image analysis for pedestrian detection
(2006)
Kelly, Philip; Cooke, Eddie; O'Connor, Noel E.; Smeaton, Alan F.
Abstract:
A method for solving the dense disparity stereo correspondence problem is presented in this paper. This technique is designed specifically for pedestrian detection type applications. A new Ground Control Points (GCPs) scheme is introduced, using groundplane homography information to determine regions in which good GCPs are likely to occur. The method also introduces a dynamic disparity limit constraint to further improve GCP selection and dense disparity generation. The technique is applied to a real world pedestrian detection scenario with a background modeling system based on disparity and edges.
http://doras.dcu.ie/381/
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3D multi-agent models for protein release from PLGA spherical particles with complex inner morphologies
(2008)
Barat, Ana; Ruskin, Heather J.; Crane, Martin
3D multi-agent models for protein release from PLGA spherical particles with complex inner morphologies
(2008)
Barat, Ana; Ruskin, Heather J.; Crane, Martin
Abstract:
In order to better understand and predict the release of proteins from bioerodible micro- or nanospheres, it is important to know the influences of different initial factors on the release mechanisms. Often though it is difficult to assess what exactly is at the origin of a certain dissolution profile. We propose here a new class of fine-grained multi-agent models built to incorporate increasing complexity, permitting the exploration of the role of different parameters, especially that of the internal morphology of the spheres, in the exhibited release profile. This approach, based on Monte-Carlo (MC) and Cellular Automata (CA) techniques, has permitted the testing of various assumptions and hypotheses about several experimental systems of nanospheres encapsulating proteins. Results have confirmed that this modelling approach has increased the resolution over the complexity involved, opening promising perspectives for future developments, especially complementing in vitro experiment...
http://doras.dcu.ie/14980/
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3D object retrieval and segmentation: various approaches including 2D poisson histograms and 3D electrical charge distributions.
(2014)
Alizadeh, Fattah
3D object retrieval and segmentation: various approaches including 2D poisson histograms and 3D electrical charge distributions.
(2014)
Alizadeh, Fattah
Abstract:
Nowadays 3D models play an important role in many applications: viz. games, cultural heritage, medical imaging etc. Due to the fast growth in the number of available 3D models, understanding, searching and retrieving such models have become interesting fields within computer vision. In order to search and retrieve 3D models, we present two different approaches: one is based on solving the Poisson Equation over 2D silhouettes of the models. This method uses 60 different silhouettes, which are automatically extracted from different viewangles. Solving the Poisson equation for each silhouette assigns a number to each pixel as its signature. Accumulating these signatures generates a final histogram-based descriptor for each silhouette, which we call a SilPH (Silhouette Poisson Histogram). For the second approach, we propose two new robust shape descriptors based on the distribution of charge density on the surface of a 3D model. The Finite Element Method is used to calculate the charg...
http://doras.dcu.ie/20075/
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3D transient thermal modelling of laser microchannel fabrication in lime-soda glass
(2008)
Issa, Ahmed A.A.; Brabazon, Dermot; Hashmi, Saleem
3D transient thermal modelling of laser microchannel fabrication in lime-soda glass
(2008)
Issa, Ahmed A.A.; Brabazon, Dermot; Hashmi, Saleem
Abstract:
Laser-fabricated microchannels in glass offer a wide range of bioengineering and telecommunication applications. A 1.5 kW CO2 laser with 10.6 μm wavelength was used in this study to fabricate micorchannels on the surface of soda-lime glass sheets. A thermal model of the process was developed based on transient heat conduction due to a pulsed heat input. The resulting equation predicted the temperature distribution in the regions surrounding the laser focus. Temperature – time curves were drawn from those equations, which were useful in estimating the thermal history in the processed samples. The temperature distribution was also used to predict the channel geometry (based on the vaporisation temperature of glass). Most of the laser power used was consumed in bringing the glass to the vaporisation temperature. The model was able to predict the channel width, depth and surface roughness. These laser-fabricated channel characteristics were measured and compared to the results obtained ...
http://doras.dcu.ie/20057/
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3p photoabsorption of free and bound Cr, Cr⁺, Mn, and Mn⁺
(1991)
Costello, John T.; Kennedy, Eugene T.; Sonntag, B.; Clark, C.
3p photoabsorption of free and bound Cr, Cr⁺, Mn, and Mn⁺
(1991)
Costello, John T.; Kennedy, Eugene T.; Sonntag, B.; Clark, C.
Abstract:
A dual-laser-plasma technique has been used to measure photoabsorption by atomic Cr and Mn and their ions at photon energies between 40 and 70 eV, where the dominant absorption mechanism is excitation of the 3p subshell. No dramatic differences are observed between the absorption spectra of Mn and Mn+, and these spectra are similar to those of Mn metal and MnCl2. The spectra of Cr and Cr+ are strikingly dissimilar, the mean excitation energy being about 5 eV greater in the ion. We attribute this to strong mixing of the localized 3d6 configuration with 3d5nd Rydberg configurations, an effect that is also responsible for the anomalous appearance of the Cr spectrum with respect to those of the other iron-period elements. The absorption spectra of Cr metal and CrCl2 take forms intermediate between those of Cr and Cr+. We give spectroscopic assignments to most of the sharp absorption features of Cr+ and determine the 3p ionization thresholds from quantum-defect analysis.
http://doras.dcu.ie/15620/
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3p photoabsorption spectra of Mn2+ and Mn3+
(2007)
Kilbane, Deirdre; Mayo, R.; van Kampen, Paul; Mosnier, Jean-Paul; Kennedy, Eugene T.; C...
3p photoabsorption spectra of Mn2+ and Mn3+
(2007)
Kilbane, Deirdre; Mayo, R.; van Kampen, Paul; Mosnier, Jean-Paul; Kennedy, Eugene T.; Costello, John T.
Abstract:
Time resolved EUV photoabsorption spectra of a manganese plasma have been recorded using the dual laser plasma technique. The 43 - 73 eV photon energy range is dominated by the 3p-3d giant resonance and to a lesser extent the 3p-4s resonances in both Mn2+ and Mn3+, recorded at an interplasma time delay of 80 ns and 30 ns respectively. These experimentally observed resonances are well reproduced by synthetic spectra calculated using the Hartree-Fock method. The synthetic spectra allow for absorption from excited states of the Mn2+ and Mn3+ ions.
http://doras.dcu.ie/98/
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3PLY - Exploring the potential for transformative workplace learning for and by teachers
(2014)
Kamp, Annelies; Black, Dorothy; Abbott, Lesley
3PLY - Exploring the potential for transformative workplace learning for and by teachers
(2014)
Kamp, Annelies; Black, Dorothy; Abbott, Lesley
Abstract:
In the context of changes to the educational settlement (Vickers 2008) and an increasing overlap of education and work, this research project concerns the learning that happens on the part of teachers and students ‘around’ workplace learning initiatives associated with the senior years of second level schooling across the island of Ireland. The field research was undertaken in two schools in the Republic of Ireland and four schools in Northern Ireland during the period between September and November 2013. Further data was generated by way of desktop research of policy documents and extant research, and through the circulation of online surveys with the support of the Institute of Guidance Counsellors in the Republic of Ireland and the Northern Ireland Schools’ Careers Association. The researchers make a number of recommendations around resourcing, timetabling and management; professional development; collaboration; communication and assessment.
http://doras.dcu.ie/19879/
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4 f(P1) giant dipole resonance in La³⁺
(1995)
Köble, Ulrich; Kiernan, Laurence; Costello, John T.; Mosnier, Jean-Paul; Kennedy, Eugen...
4 f(P1) giant dipole resonance in La³⁺
(1995)
Köble, Ulrich; Kiernan, Laurence; Costello, John T.; Mosnier, Jean-Paul; Kennedy, Eugene T.; Ivanov, V.; Kupchenko, V.; Shendrik, M.
Abstract:
Photoabsorption of free La3+ ions in the 4d excitation region has been measured using the dual-laser plasma technique. A dramatic strong and broad 4d94f(1P) giant dipole resonance was observed. The interpretation of the results is provided using theoretical techniques which go beyond the independent particle approximation. In particular the strong term dependence for 4f(1P) gives evidence of strong polarization effects for the description of the giant dipole resonance.
http://doras.dcu.ie/15617/
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4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate
(1993)
Ferguson, George; Gallagher, John F.; Vogt, Walter; Phillips, James; Williams, Graheme ...
4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate
(1993)
Ferguson, George; Gallagher, John F.; Vogt, Walter; Phillips, James; Williams, Graheme J.B.
Abstract:
The 4-methyl-2,6-bis(phosphomethyl)phenol molecule, which crystallizes with two water molecules per asymmetric unit, has approximate twofold symmetry and is involved in extensive three-dimensional hydrogen bonding in which every available OH group participates. The principal dimensions include P--O 1.4981 (13) and 1.5015 (14) ,~, four P--OH distances in the range 1.5395(14) to 1.5688(13) A, P--C 1.7857(17) and 1.7893 (17) ~k, and O...O intramolecular and intermolecular hydro.gen-bond distances in the range 2.458 (2) to 2.866 (2) A.
http://doras.dcu.ie/3627/
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4',5',6',7'-Tetrachlorospiro[cyclohex-2-ene-1,2'-indan]-1',3'-dione
(2005)
McSweeney, Nigel; Pratt, Albert C.; Long, Conor; Howie, R. Alan
4',5',6',7'-Tetrachlorospiro[cyclohex-2-ene-1,2'-indan]-1',3'-dione
(2005)
McSweeney, Nigel; Pratt, Albert C.; Long, Conor; Howie, R. Alan
Abstract:
The title compound, C₁₄H₈Cl₄O₂, has been isolated following irradiation of a dichloromethane solution of N-acetyltetrachlorophthalimide and cyclohexene. The structure refinement is slightly compromised by the disorder over two positions of equal occupancy of a methylene groupβ to the spiro C atom.
http://doras.dcu.ie/117/
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4p-inner-shell and double-excitation spectrum of Sr II
(2009)
Banahan, Caroline; Costello, John T.; Kilbane, Deirdre; van Kampen, Paul
4p-inner-shell and double-excitation spectrum of Sr II
(2009)
Banahan, Caroline; Costello, John T.; Kilbane, Deirdre; van Kampen, Paul
Abstract:
We report photoabsorption measurements from the 4p inner shell of singly ionized strontium in the spectral region between 26.0 and 37.4 eV. More than 60 levels of Sr II are reported which are interpreted as singly excited inner-shell transitions 4p65s 2S1∕2→4p45s(1P,3P)ns, md and doubly excited transitions 4p65s 2S1∕2→4p54d(1P,3P,3D)nl. Multiconfiguration Hartree-Fock calculations are performed in jj coupling and the levels are arranged into Rydberg series converging on seven limits, allowing the identification of two levels in Sr III.
http://doras.dcu.ie/15659/
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5',6-Dichloro-1',3',3'-trimethylspiro[2H-1-benzopyran-2,2'-indoline]
(2008)
Alhashimy, Nameer; Müller-Bunz, Helge; Schazmann, Benjamin ; Diamond, Dermot
5',6-Dichloro-1',3',3'-trimethylspiro[2H-1-benzopyran-2,2'-indoline]
(2008)
Alhashimy, Nameer; Müller-Bunz, Helge; Schazmann, Benjamin ; Diamond, Dermot
Abstract:
In the crystal structure of the title compound, C19H17Cl2NO, the indoline and benzopyran ring systems are approximately perpendicular to each other. The indoline ring is in an envelope conformation with the spiro C atom as the flap. The N atom of the indoline ring forms a pyramidal environment, the sum of the angles at this atom being 352.46°.
http://doras.dcu.ie/714/
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6-(4-Fluorophenyl)-8-phenyl-2,3-dihydro-4H-imidazo[5,1-b][1,3]thiazin-4-one: an unusual [6-5] fused-ring system
(2007)
Gallagher, John F.; Le Bas, Marie-Delphine H.; Coleman, Claire M.; O'Shea, Donal F.
6-(4-Fluorophenyl)-8-phenyl-2,3-dihydro-4H-imidazo[5,1-b][1,3]thiazin-4-one: an unusual [6-5] fused-ring system
(2007)
Gallagher, John F.; Le Bas, Marie-Delphine H.; Coleman, Claire M.; O'Shea, Donal F.
Abstract:
The title compound, C₁₈H₁₃FN₂OS, is the first structural example of a [6-5] fused ring incorporating the 2,3-dihydro-4H-imidazo[5,1-b][1,3]thiazin-4-one molecular scaffold. The six-membered 2,3-dihydro-1,3-thiazin-4-one ring adopts an envelope conformation, with the S-CH₂ C atom displaced by 0.761 (2) Å from the five-atom plane (all within 0.05 Å of the mean plane). The imidazole ring is planar. The phenyl ring is twisted from coplanarity with the imidazole ring by 23.84 (5)° and the 4-fluorophenyl ring is twisted by 53.36 (6)°, due to a close C(aryl)-H...O=C contact with the thiazin-4-one carbonyl O atom. The primary intermolecular interaction involves a CH₂ group with the F atom [C...F = 3.256 (2) Å and C-H...F = 137°].
http://doras.dcu.ie/303/
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