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Subject = DIMETHYL ETHER;
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Displaying Results 1 - 10 of 10 on page 1 of 1
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A comparative study of the effect of varied reaction environments on a swirl stabilized flame geometry via optical measurements
(2019)
Banyon, Colin; Rodriguez-Henriquez, Jose J.; Paterakis, George; Malliotakis, Zisis; Sou...
A comparative study of the effect of varied reaction environments on a swirl stabilized flame geometry via optical measurements
(2019)
Banyon, Colin; Rodriguez-Henriquez, Jose J.; Paterakis, George; Malliotakis, Zisis; Souflas, Konstantinos; Keramiotis, Christos; Vourliotakis, George; Mauss, Fabian; Curran, Henry J.; Skevis, George; Koutmos, Panagiotis; Founti, Maria
Abstract:
The present work is a part of a larger experimental campaign which examines the behaviour of various fuels on a swirl stabilized flame burner configuration. Overall, detailed speciation measurements and temperature measurements were combined with optical measurements. The work presented here concerns the part of the experimental campaign which deals with the optical characteristics of the examined flames. The work adds to the growing database of experimental measurements assessing engine-relevant reaction environments which shift from traditional ones in order to meet pollutant emission regulations and efficiency standards. Here, the oxidation of several commonly used fuel and fuel surrogates that are subjected to the addition of a bio-derived fuel additive (dimethyl ether) and emulated exhaust gas recirculation (EGR) is studied in a laboratory-scale swirl stabilized burner. The natural flame chemiluminescence has been exploited to selectively measure line of sight CH* and OH* profi...
http://hdl.handle.net/10379/14789
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A comprehensive experimental and modeling study of isobutene oxidation
(2016)
Zhou, Chong-Wen; Li, Yang; O'Connor, Eoin; Somers, Kieran P.; Thion, Sébastien; Ke...
A comprehensive experimental and modeling study of isobutene oxidation
(2016)
Zhou, Chong-Wen; Li, Yang; O'Connor, Eoin; Somers, Kieran P.; Thion, Sébastien; Keesee, Charles; Mathieu, Olivier; Petersen, Eric L.; DeVerter, Trent A.; Oehlschlaeger, Matthew A.; Kukkadapu, Goutham; Sung, Chih-Jen; Alrefae, Majed; Khaled, Fathi; Farooq, Aamir; Dirrenberger, Patricia; Glaude, Pierre-Alexandre Glaude; Battin-Leclerc, Frédérique; Santner, Jeffrey; Ju, Yiguang
Abstract:
Isobutene is an important intermediate in the pyrolysis and oxidation of higher-order branched alkanes, and it is also a component of commercial gasolines. To better understand its combustion characteristics, a series of ignition delay time (IDT) and laminar flame speed (LFS) measurements have been performed. In addition, flow reactor speciation data recorded for the pyrolysis and oxidation of isobutene is also reported. Predictions of an updated kinetic model described herein are compared with each of these data sets, as well as with existing jet-stirred reactor (JSR) species measurements.IDTs of isobutene oxidation were measured in four different shock tubes and in two rapid compression machines (RCMs) under conditions of relevance to practical combustors. The combination of shock tube and RCM data greatly expands the range of available validation data for isobutene oxidation models to pressures of 50 atm and temperatures in the range 666-1715 K. Isobutene flame speeds were measur...
http://hdl.handle.net/10379/6030
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A comprehensive experimental and modeling study of isobutene oxidation
(2018)
Zhou, Chong-Wen; Li, Yang; O'Connor, Eoin; Somers, Kieran P.; Thion, Sébastien; Ke...
A comprehensive experimental and modeling study of isobutene oxidation
(2018)
Zhou, Chong-Wen; Li, Yang; O'Connor, Eoin; Somers, Kieran P.; Thion, Sébastien; Keesee, Charles; Mathieu, Olivier; Petersen, Eric L.; DeVerter, Trent A.; Oehlschlaeger, Matthew A.; Kukkadapu, Goutham; Sung, Chih-Jen; Alrefae, Majed; Khaled, Fathi; Farooq, Aamir; Dirrenberger, Patricia; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique; Santner, Jeffrey; Ju, Yiguang
http://hdl.handle.net/10379/14536
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An experimental and chemical kinetic modeling study of 1,3-butadiene combustion: Ignition delay time and laminar flame speed measurements
(2019)
Zhou, Chong-Wen; Li, Yang; Burke, Ultan; Banyon, Colin; Somers, Kieran P.; Ding, Shuiti...
An experimental and chemical kinetic modeling study of 1,3-butadiene combustion: Ignition delay time and laminar flame speed measurements
(2019)
Zhou, Chong-Wen; Li, Yang; Burke, Ultan; Banyon, Colin; Somers, Kieran P.; Ding, Shuiting; Khan, Saadat; Hargis, Joshua W.; Sikes, Travis; Mathieu, Olivier; Petersen, Eric L.; AlAbbad, Mohammed; Farooq, Aamir; Pan, Youshun; Zhang, Yingjia; Huang, Zuohua; Lopez, Joseph; Loparo, Zachary; Vasu, Subith S.; Curran, Henry J.
Abstract:
Ignition delay times for 1,3-butadiene oxidation were measured in five different shock tubes and in a rapid compression machine (RCM) at thermodynamic conditions relevant to practical combustors. The ignition delay times were measured at equivalence ratios of 0.5, 1.0, and 2.0 in 'air' at pressures of 10, 20 and 40 atm in both the shock tubes and in the RCM. Additional measurements were made at equivalence ratios of 0.3, 0.5, 1.0 and 2.0 in argon, at pressures of 1, 2 and 4 atm in a number of different shock tubes. Laminar flame speeds were measured at unburnt temperatures of 295 K, 359 K and 399 K at atmospheric pressure in the equivalence ratio range of 0.6-1.7, and at a pressure of 5 atm at equivalence ratios in the range 0.6-1.4. These experimental data were then used as validation targets for a newly developed detailed chemical kinetic mechanism for 1,3-butadiene oxidation.A detailed chemical kinetic mechanism (AramcoMech 3.0) has been developed to describe the combus...
http://hdl.handle.net/10379/14784
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An experimental and modeling study of propene oxidation. part 2: ignition delay time and flame speed measurements
(2018)
Burke, Sinéad M.; Burke, Ultan; Mc Donagh, Reuben; Mathieu, Olivier; Osorio, Irmis; Kee...
An experimental and modeling study of propene oxidation. part 2: ignition delay time and flame speed measurements
(2018)
Burke, Sinéad M.; Burke, Ultan; Mc Donagh, Reuben; Mathieu, Olivier; Osorio, Irmis; Keesee, Charles; Morones, Anibal; Petersen, Eric L.; Wang, Weijing; DeVerter, Trent A.; Oehlschlaeger, Matthew A.; Rhodes, Brandie; Hanson, Ronald K.; Davidson, David F.; Weber, Bryan W.; Sung, Chih-Jen; Santner, Jeffrey; Ju, Yiguang; Haas, Francis M.; Dryer, Frederick L.
http://hdl.handle.net/10379/10608
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An ignition delay and kinetic modeling study of methane, dimethyl ether, and their mixtures at high pressures
(2016)
Burke, Ultan; Somers, Kieran P.; O’Toole, Peter; Zinner, Chis M.; Marquet, Nicolas; Bou...
An ignition delay and kinetic modeling study of methane, dimethyl ether, and their mixtures at high pressures
(2016)
Burke, Ultan; Somers, Kieran P.; O’Toole, Peter; Zinner, Chis M.; Marquet, Nicolas; Bourque, Gilles; Petersen, Eric L.; Metcalfe, Wayne K.; Serinyel, Zeynep; Curran, Henry J.
Abstract:
Journal article
The development of accurate chemical kinetic models capable of predicting the combustion of methane and dimethyl ether in common combustion environments such as compression ignition engines and gas turbines is important as it provides valuable data and understanding of these fuels under conditions that are difficult and expensive to study in the real combustors. In this work, both experimental and chemical kinetic model-predicted ignition delay time data are provided covering a range of conditions relevant to gas turbine environments (T = 600-1600 K, p = 7-41 atm, phi = 0.3, 0.5, 1.0, and 2.0 in 'air' mixtures). The detailed chemical kinetic model (Mech_56.54) is capable of accurately predicting this wide range of data, and it is the first mechanism to incorporate high-level rate constant measurements and calculations where available for the reactions of DME. This mechanism is also the first to apply a pressure-dependent treatment to the low-temperature...
http://hdl.handle.net/10379/6102
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Experimental and kinetic modeling study of the shock tube ignition of a large oxygenated fuel: tri-propylene glycol mono-methyl ether
(2016)
Burke, Ultan; Pitz, William J.; Curran, Henry J.
Experimental and kinetic modeling study of the shock tube ignition of a large oxygenated fuel: tri-propylene glycol mono-methyl ether
(2016)
Burke, Ultan; Pitz, William J.; Curran, Henry J.
Abstract:
Tri-propylene glycol monomethyl ether (TPGME) is an important oxygenated fuel additive that can be used to reduce soot in diesel engines. However, a validated chemical kinetic model that incorporates the low- to high-temperature chemistry, needed to simulate ignition in a diesel engine is not available for TPGME. In addition, no fundamental experimental data are available that can be used to validate a TPGME mechanism. In this study, a surrogate chemical kinetic model for TPGME that includes low- and high-temperature chemistry has been developed, and shock tube ignition delay time data has been acquired for its validation at 0.25% TPGME for temperatures in the range of 980-1545 K, at pressures of 10 and 20 atm, and at equivalence ratios of phi = 0.5, 1.0 and 2.0. The predictions from the model have been compared to the experimental measurements with good agreement. Under the experimental conditions investigated in the shock tube, TPGME was found to be consumed by molecular eliminati...
http://hdl.handle.net/10379/5638
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Probing the antagonistic effect of toluene as a component in surrogate fuel models at low temperatures and high pressures. A case study of toluene/dimethyl ether mixtures
(2017)
Zhang, Yingjia; Somers, Kieran P.; Mehl, Marco; Pitz, William J.; Cracknell, Roger F.; ...
Probing the antagonistic effect of toluene as a component in surrogate fuel models at low temperatures and high pressures. A case study of toluene/dimethyl ether mixtures
(2017)
Zhang, Yingjia; Somers, Kieran P.; Mehl, Marco; Pitz, William J.; Cracknell, Roger F.; Curran, Henry J.
Abstract:
There is a dearth of experimental data which examine the fundamental low-temperature ignition (T < 900 K) behavior of toluene resulting in a lack of data for the construction, validation, and interpretation of chemical kinetic models for commercial fuels. In order to gain a better understanding of its combustion chemistry, dimethyl ether (DME) has been used as a radical initiator to induce ignition in this highly knock resistant aromatic, and its influence on the combustion of toluene ignition was studied in both shock tube and rapid compression machines as a function of temperature (624–1459 K), pressure (20–40 atm), equivalence ratio (0.5–2.0), and blending ratio (100% toluene, 76% toluene (76T/24D), 58% toluene (58T/42D), 26% toluene (26T/74D) and 100% DME). Several literature chemical kinetic models are used to interpret our experimental results. For mixtures containing high concentrations of toluene at low-temperatures none of these are capable of reproducing experiment. Th...
http://hdl.handle.net/10379/6868
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Species measurements of the particulate matter reducing additive tri–propylene glycol monomethyl ether
(2019)
Burke, Ultan; Shahla, Roya; Dagaut, Phillippe; Dayma, Guillaume; Togbé, Casimir; Somers...
Species measurements of the particulate matter reducing additive tri–propylene glycol monomethyl ether
(2019)
Burke, Ultan; Shahla, Roya; Dagaut, Phillippe; Dayma, Guillaume; Togbé, Casimir; Somers, Kieran P.; Curran, Henry J.
Abstract:
Reducing particulate matter formation and emissions by using fuel additives is a topic of interest for the petrochemical and automotive engineering industries. A compound which has been shown to be effective in this regard is tri-propylene glycol monomethyl ether (TPGME). This molecule consists of three ether linkages, an alcoholic group and alkyl branching including primary, secondary and tertiary C-H bonds. Its exotic structural features make it challenging to accurately model its oxidation. It is these same structural features that make this molecule both an exciting additive and a challenging fuel for kinetic modelers to understand. To provide insight into the oxidation of this molecule, species measurements have been performed in a jet- stirred reactor. Species concentrations are measured at three equivalence ratios; 0.5, 1.0 and 2.0, at a constant TPGME concentration of 1000 ppm, a pressure of 1 atm, a constant residence time of 70 ms and over the temperature range of 530-1250...
http://hdl.handle.net/10379/14938
Displaying Results 1 - 10 of 10 on page 1 of 1
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