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The structure of triphenylgermanium hydroxide
Ferguson, George; Gallagher, John F.; Murphy, Denis; Spalding, Trevor R.; Glidewell, Christopher; Holden, H. Diane
C18H~6GeO, Mr = 320.9, triclinic, Pi, a = 15.408 (6), b = 19.974 (7), c = 23.264 (11) A, a = 107.78 (4), 13 = 1.03.54 (4), y= 101.51 (3) °, V = 6338 (5)/~3, Z = 16, Dx = 1.34 g cm -3, a(Mo Ka) = 0.71073A, /z = 19.1cm-1, F(000)=2624, T= 293 K, R = 0.055 for 6846 observed reflections. The eight independent molecules in the asymmetric unit form two independent O--H...O hydrogen-bonded tetramers with the O atoms in a flattened tetrahedral arrangement [hydrogen-bond distances in the range 2.609 (11) to 2.657 (11)A]. The Ge atoms are tetrahedrally coordinated with mean Gc O 1.791 (7) and Gc C 1.931 (8) A.
Keyword(s): Organic chemistry; Crystallography
Publication Date:
1992
Type: Other
Peer-Reviewed: Unknown
Language(s): English
Institution: Dublin City University
Citation(s): Ferguson, George, Gallagher, John F. ORCID: 0000-0002-7112-7450 <https://orcid.org/0000-0002-7112-7450>, Murphy, Denis, Spalding, Trevor R., Glidewell, Christopher and Holden, H. Diane (1992) The structure of triphenylgermanium hydroxide. Acta Crystallographica Section C, 48 (7). pp. 1228-1231. ISSN 0108-2701
Publisher(s): International Union of Crystallography
File Format(s): application/pdf
Related Link(s): http://doras.dcu.ie/3611/1/acta_crys_c_48_7.pdf,
http://dx.doi.org/10.1107/S0108270191015056
First Indexed: 2009-11-05 02:01:24 Last Updated: 2019-02-09 06:59:48