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Mesoionic oxides: facile access from triazolium salts or triazolylidene copper precursors and, catalytic relevance
Petronilho, Ana; Müller-Bunz, Helge; Albrecht, Martin
Reaction of CsOH with triazolium salts affords mesoionic compounds containing an exocyclic oxygen; the same product is obtained by reaction of the corresponding Cu(I) triazolylidenes with CsOH and represents an unusual reactivity pattern of N-heterocyclic carbene precursors that has implications for carbene copper-catalyzed reactions. European Research Council Science Foundation Ireland
Keyword(s): Catalysis; Copper; Synthetic methodology
Publication Date:
2015
Type: Journal article
Peer-Reviewed: Unknown
Language(s): English
Institution: University College Dublin
Publisher(s): Royal Society of Chemistry
First Indexed: 2015-06-17 05:15:21 Last Updated: 2018-10-11 15:33:25