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A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of a NHC-Rh hydrosilylation catalyst
Monney, Angèle; Albrecht, Martin
Coupling of a histidinium salt with a MetAlaAla amino acid sequence followed by metallation with [RhCl(cod)]2 yields a rhodium(I) NHC complex with a pending peptide residue. Methionine chelation, induced by chloride abstraction from the metal coordination sphere, affords an efficient hydrosilylation catalyst precursor comprised of a peptidic macrocyclic chelate backbone. European Research Council Swiss National Science Foundation
Keyword(s): Organometallic entities; Bioorganometallic chemistry
Publication Date:
2015
Type: Journal article
Peer-Reviewed: Unknown
Language(s): English
Institution: University College Dublin
Publisher(s): Royal Society of Chemistry
First Indexed: 2015-08-20 05:35:01 Last Updated: 2018-10-11 15:33:24