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Evaluating the performance of nanostructured materials as lithium-ion battery electrodes
Armstrong, Mark J.; O'Dwyer, Colm; Macklin, William J.; Holmes, Justin D.
The performance of the lithium-ion cell is heavily dependent on the ability of the host electrodes to accommodate and release Li+ ions from the local structure. While the choice of electrode materials may define parameters such as cell potential and capacity, the process of intercalation may be physically limited by the rate of solid-state Li+ diffusion. Increased diffusion rates in lithium-ion electrodes may be achieved through a reduction in the diffusion path, accomplished by a scaling of the respective electrode dimensions. In addition, some electrodes may undergo large volume changes associated with charging and discharging, the strain of which, may be better accommodated through nanostructuring. Failure of the host to accommodate such volume changes may lead to pulverisation of the local structure and a rapid loss of capacity. In this review article, we seek to highlight a number of significant gains in the development of nanostructured lithium-ion battery architectures (both anode and cathode), as drivers of potential next-generation electrochemical energy storage devices.
Keyword(s): Lithium ion batteries; Nanostructuring; Anodes; Cathodes
Publication Date:
2013
Type: Journal article
Peer-Reviewed: Yes
Language(s): English
Institution: University College Cork
Funder(s): Science Foundation Ireland
Citation(s): ARMSTRONG, M. J., O’DWYER, C., MACKLIN, W. J. & HOLMES, J. D. 2013. Evaluating the performance of nanostructured materials as lithium-ion battery electrodes. Nano Research, 7, 1-62. http://dx.doi.org/10.1007/s12274-013-0375-x
Publisher(s): Springer Verlag & Tsingua University Press
File Format(s): application/pdf
Related Link(s): http://www.springer.com/materials/nanotechnology/journal/12274
First Indexed: 2016-07-13 05:44:23 Last Updated: 2016-10-14 06:02:52