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Reactions of 1,4-bis(tetrazole)benzenes: formation of long chain alkyl halides
McGinley, John; Bond, Andrew; Fleming, Adrienne; Kelleher, Fintan; Prajapati, Vipa
The reactions of 1,4-bis[2-(tributylstannyl)tetrazol-5-yl]benzene with α,ω-dibromoalkanes were carried out in order to synthesise pendant alkyl halide derivatives of the parent bis-tetrazole. This led to the formation of several alkyl halide derivatives, substituted variously at N1 or N2 on the tetrazole ring. The crystal structures of 1,4-bis[(2-(4-bromobutyl)tetrazol-5-yl)]benzene (2-N,2-N′), 1,4-bis[(2-(4-bromobutyl)tetrazol-5-yl)]benzene (1-N,2-N′) and 1,4-bis[(2-(8-bromooctyl)tetrazol-5-yl)]benzene (2-N,2-N′) are reported. Further discussion involves the structure of 1,4-bis[2-(6-bromohexyl)-2H-tetrazol-5-yl]benzene (2-N,2-N′) previously reported.
Keyword(s): Chemistry; Tetrazole; Organotin; X-ray; Alkyl halide; NMR spectroscopy
Publication Date:
Type: Journal article
Peer-Reviewed: Yes
Institution: Maynooth University
Citation(s): McGinley, John and Bond, Andrew and Fleming, Adrienne and Kelleher, Fintan and Prajapati, Vipa (2006) Reactions of 1,4-bis(tetrazole)benzenes: formation of long chain alkyl halides. Tetrahedron, 62 (4). pp. 9577-9581.
Publisher(s): Elsevier
File Format(s): application/pdf
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First Indexed: 2020-01-31 06:08:27 Last Updated: 2021-07-31 09:01:59