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Methyl 2-[(ferrocenylcarbonyl)amino]thiophene-3-carboxylate
Alley, Steven; Gallagher, John F.; Kenny, Peter T.M.; Lough, Alan J.
The title compound, [Fe(C₅H₅)(C₁₂H₁₀NO₃S)], was synthesized from ferrocenecarboxylic acid and methyl 2-aminothiophene-3-carboxylate in modest yield. The substituted ring system is essentially planar through the amidothienylcarboxylate moiety, η⁵-(C₅H₄)CONH(C₄H₂S)CO₂Me, with the amido unit at an angle of 3.60 (7)° to the five-atom thienyl group, which is oriented at an angle of 3.17 (7)° to the ester moiety. The primary hydrogen bond is an intramolecular N-H...O=Ccarboxylate interaction [N...O 2.727 (2) Å], and the main intermolecular hydrogen bond involves a thienyl carboxylate and the carboxylate of a symmetry-related molecule [C...O 3.443 (3) Å].
Keyword(s): Organic chemistry; Chemistry; Crystallography
Publication Date:
2005
Type: Other
Peer-Reviewed: Unknown
Language(s): English
Institution: Dublin City University
Citation(s): Alley, Steven, Gallagher, John F. ORCID: 0000-0003-4130-4556 <https://orcid.org/0000-0003-4130-4556>, Kenny, Peter T.M. and Lough, Alan J. (2005) Methyl 2-[(ferrocenylcarbonyl)amino]thiophene-3-carboxylate. Acta Crystallographica Section E, 61 (2). pp. 201-203. ISSN 1600-5368
Publisher(s): International Union of Crystallography
File Format(s): application/pdf
Related Link(s): http://doras.dcu.ie/124/1/acta_crys_e_61_2.pdf,
http://dx.doi.org/10.1107/S1600536804033355
First Indexed: 2009-11-05 02:00:17 Last Updated: 2019-02-09 07:05:31