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A new, mild one-pot synthesis of iodinated heterocycles as suitable precursors for N-heterocyclic carbene complexes
Iglesias, Manuel; Schuster, Oliver; Albrecht, Martin
The use of I2/AgOAc in dichloromethane constitutes a cheap, mild, and efficient method for the selective iodination of a variety of heterocycles. In a number of cases, this method provides superior yields than other literature methods and affords iodo-functionalized heterocycles that are suitable precursors for carbene complexes. European Research Council Swiss National Science Foundation FP7 (Marie Curie Action)
Keyword(s): Iodination; Imidazole; N-heterocyclic carbene; Oxidative addition; Ligand precursors; Abnormal carbene complexes; Heterocyclic compounds; Imidazoles; Carbenes (Methylene compounds)
Publication Date:
Type: Journal article
Peer-Reviewed: Unknown
Language(s): English
Institution: University College Dublin
Publisher(s): Elsevier
File Format(s): other; application/pdf
First Indexed: 2012-08-25 05:15:22 Last Updated: 2018-10-11 15:54:11