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Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes
Iglesias, Manuel; Albrecht, Martin
Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic complexes by using 31P NMR spectroscopy as a convenient probe for their donor ability and in catalytic cross-coupling reactions. European Research Council COST D40 Swiss National Science Foundation
Keyword(s): Abnormal carbene; Isoxazolylidene; Palladium; Donor properties; Cross-coupling catalysis; Carbenes (Methylene compounds); Catalysis
Publication Date:
2012
Type: Journal article
Peer-Reviewed: Unknown
Language(s): English
Institution: University College Dublin
Publisher(s): RSC Publishing
File Format(s): other; application/pdf
First Indexed: 2012-08-25 05:15:23 Last Updated: 2018-10-11 15:54:13