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The chemistry of group 6 metal carbonyls with N-Donor ligands
Hegarty, Cormac
The behaviour of the photochemically produced tungsten pentacarbonyl is investigated by laser flash photolysis and conventional ultraviolet/visible spectrophotometric methods. Rate constants for their reactions with 2- and 4-picoline and other pyridine derivatives are reported along with their proposed mechanisms. W(CO)5(L) complexes (L = pyridine, 2- or 4-phenylpyridine, or 2,2¬ędipyridylamine) are synthesised along with 3,6-bis(2-pyridyl)-l,4-dihydro-l,2,4,5-tetrazene derivatives of M(CO)6 (M = Cr, Mo, or W) These complexes are characterised by infrared, ultraviolet/visible, proton nuclear magnetic resonance spectroscopy, and by X-ray diffraction analysis Attempts to synthesise the W(CO)5(L) complexes (L = 2- aminomethylpyridine or bispicoylamine) were also reported The solvatochromie behaviour of these penta and tetra-carbonyl complexes was also investigated.
Keyword(s): Chemistry; Carbonyl compounds; Tungsten pentacarbonyl
Publication Date:
Type: Other
Peer-Reviewed: Unknown
Language(s): English
Contributor(s): Long, Conor
Institution: Dublin City University
Citation(s): Hegarty, Cormac (1989) The chemistry of group 6 metal carbonyls with N-Donor ligands. Master of Science thesis, Dublin City University.
Publisher(s): Dublin City University. School of Chemical Sciences
File Format(s): application/pdf
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First Indexed: 2013-08-20 05:08:04 Last Updated: 2019-02-09 06:32:06