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Synthesis of Orthogonally Protected Azalanthionines (Lanazanines) by Sequential Ring-Opening of N-Substituted Aziridine 2-Carboxylates
O'Brien, Keith; Ó Proinsias, Keith; Kelleher, Fintan
Orthogonally protected azalanthionines (lanazanines, 4-azadiaminopimelic acids or b-aminoalaninoalanines) have been synthesised in good yields by the ring-opening of N-protected aziridine 2-carboxylates with suitably protected diaminopropanoic acids (DAPs). The required DAPs were also synthesised by ring-opening of N-protected aziridine 2-carboxylates with para-methoxybenzylamine.
Keyword(s): Azalanthionine; Lanthionine; Aziridine; Ring-opening; orthogonal protection; Organic Chemistry
Publication Date:
Type: Other
Peer-Reviewed: Unknown
Contributor(s): Irish Government; PRTLI III and IV; Strand 1 of Technological Sector Research Programme
Institution: Dublin Institute of Technology
Citation(s): Articles
Publisher(s): Dublin Institute of Technology
File Format(s): application/pdf
First Indexed: 2013-10-16 05:52:25 Last Updated: 2017-12-14 06:57:24