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Regioselective functionalization of tetrabromophenanthroline-ruthenium complexes
Rau, Sven; Fischer, Reinald; Jäger, Michael; Schäfer, Bernhard; Meyer, Susann; Kreisel, Günter; Görls, Helmar; Rudolf, Manfred; Henry, William; Vos, Johannes G.
Structural, photophysical and -chemical characterisation and reactivity of a novel polypyridyl ruthenium complex based on 3,5,6,8-tetra-bromophenanthroline are discussed. Signal storage at a molecular level is great challenge for chemistry.1 The possibility of connecting different functionalities selectively to one ligand of a metal complex may open the route towards higher integrated molecular units capable of processing various external stimuli in a predesignated order. The implementation of this concept demands ligands with a multitude of potential connecting groups which can selectively be transformed.2 3-bromo- and 3,8-dibromophenanthrolines have proved useful for the preparation of mononuclear3 and multiheteronuclear complexes.4 These systems have found applications ranging from DNA photoprobes5 to metalloligands in catalysis.6 A very useful feature of this bromophenanthroline ruthenium complexes is their susceptibility towards nucleophilic aromatic substitution which is very well established.
Keyword(s): Chemistry; ruthenium; nucleophilic substitution; phenanthroline
Publication Date:
2004
Type: Other
Peer-Reviewed: Unknown
Language(s): English
Institution: Dublin City University
Citation(s): Rau, Sven, Fischer, Reinald, Jäger, Michael, Schäfer, Bernhard, Meyer, Susann, Kreisel, Günter, Görls, Helmar, Rudolf, Manfred, Henry, William and Vos, Johannes G. (2004) Regioselective functionalization of tetrabromophenanthroline-ruthenium complexes. European Journal of Inorganic Chemistry, 2004 (10). pp. 2001-2003. ISSN 1434-1948
Publisher(s): John Wiley & Sons
File Format(s): application/pdf
Related Link(s): http://doras.dcu.ie/35/1/Regioselective_functionalisation_of_tetrabromo_-_Europen_Journal_of_Inorganic_Chemistry.pdf,
http://dx.doi.org/10.1002/ejic.200400163
First Indexed: 2014-04-17 05:43:19 Last Updated: 2019-02-09 06:10:49