Institutions | About Us | Help | Gaeilge
rian logo


Mark
Go Back
{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate
MCCABE, THOMAS; MARZEC, BARTOSZ; SCHMITT, WOLFGANG
The title compound, [CuCl2(C18H18N8)]?2CH3OH?H2O, contains a pentacoordinated Cu(II) atom bonded to the tridentate 4,6-bis[(E)-1-methyl-2-(pyridin-2-ylmethylidene)hydrazinyl]pyrimidine ligand and two Cl atoms. The geometry around the CuII atom is distorted square-pyramidal. The molecules pack in the crystal structure via O-HCl, O-HN, C-HCl and C-HO hydrogen bonds, C-H and - interactions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine interactions are 3.750 (3) and 3.850 (3) ?, respectively], forming sheet-like assemblies.
Keyword(s): Chemistry; Crystallography; Nanoscience & Materials
Publication Date:
2011
Type: Journal article
Peer-Reviewed: Yes
Language(s): English
Institution: Trinity College Dublin
Citation(s): Marzec B, Mariyatra MB, McCabe T, Schmitt W, {4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate, Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1073-m1074
First Indexed: 2014-05-13 05:19:49 Last Updated: 2015-07-15 05:30:03