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2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide
Gallagher, John F.; Alley, Steven; Lough, Alan J.
The title compound, [Fe2(C5H5)2(C30H22N2O2)], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methylpyridine, forms a twisted molecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intramolecular C-H...[pi] interaction is observed involving a substituted [eta]5-C5H4 ring and an ortho H atom of the benzene ring on the opposite side of the molecule. In the crystal structure, there are no classical hydrogen bonds: interactions comprise a short C6-H...[pi](C6) interaction involving substituted benzene rings and two C-H...O=C interactions per molecule.
Keyword(s): Organic chemistry; Crystallography
Publication Date:
2009
Type: Other
Peer-Reviewed: Unknown
Language(s): English
Institution: Dublin City University
Citation(s): Gallagher, John F. ORCID: 0000-0003-4130-4556 <https://orcid.org/0000-0003-4130-4556>, Alley, Steven and Lough, Alan J. (2009) 2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide. Acta Crystallographica Section E, 65 (3). ISSN 1600-5368
Publisher(s): International Union of Crystallography
File Format(s): application/pdf
Related Link(s): http://doras.dcu.ie/2442/1/acta_crys_e_65_3_2.pdf,
http://dx.doi.org/10.1107/S1600536809006278
First Indexed: 2009-11-05 02:01:19 Last Updated: 2019-02-09 07:00:05